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Episodes from the Johto League Chapions Series are available on VHS or DVD. Certain Episodes from Johto League Champions were released on VHS in special "High Voltage Collection" videos, the spotlighted action episodes. Other episodes were released in order on seven episode DVDs.
The list below shows you which episodes are available on video or DVD, though it may be difficult to find the earlier releases.
Indigo League - Orange Island Adventures - Johto Journeys - Johto League Champions - Movies
High Voltage Collection (VHS Only)
"Moonlight Showdown"
409 - Two Hits and a Miss
408 - Hassle in the Castle
414 - Power Play 
"Fire and Ice"
424 - The Tower Inferno!
425 - From Ghost to Ghost
432 - Freeze Frame
"The Hidden Temple"
416 - Wobba-Palooza
423 - Houndoom's Special Delivery
439 - Control Freak
"Crash of the Dairy"
401 - A Goldenrod Opportunity
402 - A Dairy Tale Ending
412 - Beauty and the Breeder
"Learning to be the Best"
433 - The Stolen Stones
419 - Ariados Amigos!
422 - The Apple Corps
"Big Air"
442 - Current Events
445 - The Big Balloon Blow-Up
447 - Right On, Rhydon
"Tea'd Off"
404 - The Bug Stops Here
426 - Brewing Up Trouble
437 - Ring Masters
Johto League Champions (DVD Only)
Volume 1 - Road To The Johto League
401 - A Goldenrod Opportunity
402 - A Dairy Tale Ending
403 - Air Time
404 - The Bug Stops Here
405 - Type Casting
406 - Fossil Fools
407 - Carrying On
Volume 2 - Journey To The Johto League
408 - Hassle in the Castle
409 - Two Hits and a Miss
410 - A Hot Water Battle
411 - Hook, Line and Stinker
412 - Beauty and the Breeder
413 -A Better Pill To Swallow
414 - Power Play!
Volume 3 - Distance To The Johto League
415 - Mountain Time
416 - Wobba-Palooza
417 - Imitation Confrontation
418 - The Trouble With Snubble
419 - Ariados Amigos!
420 - Wings n' Things
421 - The Grass Route
Volume 4 - Path To The Johto League
422 - The Apple Corps
423 - Houndoom's Special Delivery
424 - The Tower Inferno!
425 - From Ghost to Ghost
426 - Brewing Up Trouble
427 - All That Glitters
428 - The Light Fantastic
Volume 5 - Way To The Johto League
429 - UnBEARable!
430 - Moving Pictures
431 - Spring Fever
432 - Freeze Frame
433 - The Stolen Stones!
434 - The Dunsparse Deception
435 - The Wayward Wobbuffet
Volume 6 - Johto League
436 - Sick Daze
437 - Ring Masters
438 - The Poké Spokesman
439 - Control Freak
440 - The Art of Pokemon
441 - The Heartbreak of Brock
442 - Current Events